Publications

MOST

- Singleton, M. L.; Pirotte, G; Ferrand, Y.; Kauffmann, B.; Huc, I. “Increasing the size of an Aromatic Helical Foldamer Cavity by Strand Intercalation” Angew. Chem. Int. Ed, 2014, 53, 13140-13144.

- Singleton, M. L.; Castellucci, N.; Massip, S.; Kauffmann, B.; Ferrand, Y.; Huc, I. “Synthesis of 1,8-diazaanthracenes as Building Blocks for Internally Functionalized Aromatic Oligoamide Foldamers” J. Org. Chem. 2014, 79, 2115-2122. 

- Stoian, S. A.; Hsieh, C.-H.; Singleton, M. L.; Casuras, A. F.; Darensbourg, M. Y.; McNeely, K.; Sweely, K.; Popescu, C. V. “Hyperfine Interactions and Electron Distribution in FeIIFeI and FeIFeI Models for the Active Site of the [FeFe]-Hydrogenases: Mössbauer Spectroscopy Studies of Low-Spin FeI” J. Biol. Inorg. Chem. 2013, 18, 609-622. 

- Hsieh, C.-H.; Erdem, Ö. F.; Harman, S. D.; Singleton, M. L.; Reijerse, E.; Lubitz, W.; Popescu, C. V.; Reibenspies, J. H.; Brothers, S. M.; Hall, M. B.; Darensbourg, M. Y. “Structural and Spectroscopic Features of Mixed Valent FeIIFeI Complexes and Factors Related to the Rotated Configuration of Diiron Hydrogenase” J. Am. Chem. Soc. 2012, 134, 13089-13102. 

- Singleton, M. L.; Crouthers, D. J.; Duttweiler, R. P.; Reibenspies, J. H.; Darensbourg, M. Y. “Sulfonated Diiron Complexes as Models of the [FeFe]-Hydrogenase Enzyme Active Site” Inorg. 
Chem. 2011, 50, 5015-5026. 

- Bethel, R. D.; Singleton, M. L.; Darensbourg, M. Y. “The Modular Assembly of Clusters is the Natural Synthetic Strategy for the Active Site of [FeFe]-Hydrogenase” Angew. Chem. Int. Ed. 2010, 49, 8567-8569. 

- Singleton, M. L.; Reibenspies, J. H; Darensbourg, M. Y. “A Cyclodextrin Host-Guest Approach to a Hydrogenase Active Site Biomimetic Cavity” J. Am. Chem. Soc. 2010, 132, 8870-8871. 

- Jenkins, R. M.; Singleton, M. L.; Leamer, L. A.; Reibenspies, J. H.; Darensbourg, M. Y. “Orientation and Stereodynamic Paths of Planar Monodentate Ligands in Square Planar Nickel N2S Complexes” Inorg. Chem. 2010, 49, 5503-5514. 

- Li, B.; Liu, T.; Singleton, M. L.; Darensbourg, M. Y. “Influence of Sulf-Oxygenation on CO/L Substitution and Fe(CO)3 Rotation in Thiolate-Bridged Diiron Complexes” Inorg. Chem. 2009, 48, 8393-8403. 

- Jenkins, R. M.; Singleton, M. L.; Almaraz, E; Reibenspies, J.H.; Darensbourg, M. Y. “Imidazole-Containing Ni(N3S) Complexes Relating to Nickel Containing Biomolecules” Inorg. Chem. 2009, 48, 7280-7293. 

- Liu, T.; Li, B.; Singleton, M. L.; Hall, M. B.; Darensbourg, M. Y. “Sulfur Oxygenates of Biomimetics of the Diiron Subsite of the [FeFe]-Hydrogenase Active Site: Properties and Oxygen Damage Repair Possibilities” J. Am. Chem. Soc. 2009, 131, 8296-8307. 

- Singleton, M. L.; Bhuvanesh, N.; Reibenspies, J. H; Darensbourg, M. Y. “Synthetic Support of De Novo Design: Sterically Bulky [FeFe]-Hydrogenase Models” Angew. Chem. Int. Ed. 2008, 47, 9492-9495. 

- Singleton, M. L.; Jenkins, R. M.; Klemashevich, C. L.; Darensbourg, M. Y. “The Effect of Bridgehead Steric Bulk on the Ground State and Intramolecular Exchange Processes of (μ-SCH2CR2CH2S)[Fe(CO)3[Fe(CO)2L] complexes” C. R. Chimie. 2008, 11, 861-874. 

- Jeffery, S. P.; Singleton, M. L.; Reibenspies, J. H.; Darensbourg, M. Y. “Control of S Based Aggregation: Designed Synthesis of NiM2 and Ni2M Trinuclear Complexes” Inorg. Chem. 2007, 46, 179-185.