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IMMC

Adeline Delvaux
Contact - Personnal web page


Funding: Research assistant (UCL)
Supervisor(s): Joris Proost

Adeline obtained her master in Chemical and Materials Engineering at Université catholique de Louvain (Belgium) in 2014. Since then, she is working under the supervision of Prof. Joris Proost on the hydrogen production by water electrolysis with the view to replace actual energy sources by cleaner ones. The goal of her research consists in improving the electrochemical cell efficiency by tailoring nickel electrodes in order to favor gas bubble detachment and then reduce the overpotential due to mass transport. This is done by depositing Al-Ni alloys by magnetron co-sputtering, and then by chemically treating these alloys in a concentrated hydroxide solution with the aim of leaching out the Al. Another aspect of her research focus on the hydrogen absorption by nickel electrode during hydrogen evolution reaction. It consists in studying the hydriding mechanisms of Ni thin film electrodes into aqueous medium as well as characterize their internal stresses and microstructure effects as a function of their processing conditions since they influence kinetics and thermodynamics of hydriding.

IMMC main research direction(s):
Energy
Chemical engineering

Keywords:
electrochemical engineering
energy harvesting
thin films

Research group(s): IMAP

    

Recent publications

See complete list of publications

Journal Articles


1. Delvaux, Adeline; Lumbeeck, Gunnar; Idrissi, Hosni; Proost, Joris. Effect of microstructure and internal stress on hydrogen absorption into Ni thin film electrodes during alkaline water electrolysis. In: Electrochimica Acta, Vol. 340, p. 135970 (2020). doi:10.1016/j.electacta.2020.135970. http://hdl.handle.net/2078.1/228043

2. Proost, Joris; Delvaux, Adeline. In-situ monitoring of hydrogen absorption into Ni thin film electrodes during alkaline water electrolysis. In: Electrochimica Acta, Vol. 322, p. 134752 (2019). doi:10.1016/j.electacta.2019.134752. http://hdl.handle.net/2078.1/220236

3. Delvaux, Adeline; Van Overmeere, Quentin; Poulain, Raphaël; Proost, Joris. Enhanced Oxygen Evolution during Water Electrolysis at De-Alloyed Nickel Thin Film Electrodes. In: Journal of the Electrochemical Society, Vol. 164, no. 12, p. F1196-F1203 (2017). doi:10.1149/2.1451712jes. http://hdl.handle.net/2078.1/187731


Conference Papers


1. Delvaux, Adeline; Lumbeeck, Gunnzt; Idrissi, Hosni; Proost, Joris. Electrochemical hydrogenation of nickel thin film electrodes. In: Proceedings of the 4th International Symposium on Catalysis for Clean Energy and Sustainable Chemistry (CCESC), 2018, p. 8. http://hdl.handle.net/2078.1/210239

2. Delvaux, Adeline; Lumbeeck, G.; Schryvers, D.; Idrissi, Hosni; Proost, Joris. Nickel thin film electro-activation by hydrogen adsorption. In: Proceedings of the 8th International Conference on Hydrogen Production (ICH2P), 2017, p. 106. http://hdl.handle.net/2078.1/195825

3. Poulain, Raphaël; Delvaux, Adeline; Klein, Andreas; Proost, Joris. Reactively sputtered ultrathin nickel oxide films for electro-catalytic applications. In: Proceedings of the 6th International Symposium on Transparent Conductive Materials (TMC-2016), 2016, p. 128. http://hdl.handle.net/2078.1/179949

4. Delvaux, Adeline; Poulain, Raphaël; Van Overmeere, Quentin; Proost, Joris. Enhanced oxygen evolution from (de-)alloyed nickel thin film electrodes. In: Proceedings of the International Conference on Advances in Semiconductors and Catalysts for Photoelectrochemical Fuel Production (SolarFuel16), 2016, p. Abstract 4120. http://hdl.handle.net/2078.1/179961

5. Delvaux, Adeline; Dupuis, G.; Santoro, Ronny; Van Overmeere, Quentin; Proost, Joris. Improvement of Bubble Detachment and Overpotential during Hydrogen Evolution on (de-)alloyed Nickel Electrodes. In: Proceedings of the 67th Annual Meeting of the International Society of Electrochemistry (ISE), Symposium on Novel Materials and Devices for Energy Conversion and Storage: Fuel Cells, Electrolysers, Regenerative Fuel Cells and Flow Batteries, 2016, p. 123. http://hdl.handle.net/2078.1/180003

6. Proost, Joris; de Radiguès de Chennevières, Quentin; Delvaux, Adeline; Van Wonterghem, Frédéric. Electrochemical process intensification of hydrogen production using 3-D electrodes. In: Proceedings of the 7th International Conference on Hydrogen Technologies, Symposium on Stationary systems and applications, 2016, p. 74. http://hdl.handle.net/2078.1/180008

7. Delvaux, Adeline; Santoro, Ronny; Van Wonterghem, Frédéric; Van Overmeere, Quentin; Proost, Joris. Nickel poreux nanostructuré et évolution d’oxygène: contributions de la surface spécifique et du détachement des bulles au surpotentiel. In: Proceedings of the 17th Journées d’Electrochimie, 2015, --, p. 171. http://hdl.handle.net/2078.1/169269

8. Delvaux, Adeline; Santoro, Ronny; Van Wonterghem, Frédéric; Van Overmeere, Quentin; Proost, Joris. Enhancement of electrocatalytic activity on nanostructured porous nickel electrodes for hydrogen and oxygen evolution reactions. In: Proceedings of the 2015 Energy and Materials Research Conference (EMR-2015), 2015, --, p. 171. http://hdl.handle.net/2078.1/169295

9. Van Overmeere, Quentin; Castadot, Raphaël; Delvaux, Adeline; Proost, Joris. Influence de la stœchiométrie du TiO2 sur la performance de couches ultra-minces pour la passivation de photoanodes en silicium. In: Proceedings of the 17th Journées d’Electrochimie, 2015, --, p. 132. http://hdl.handle.net/2078.1/169286

10. Proost, Joris; Delvaux, Adeline; Delmelle, Renaud; Van Wonterghem, Frédéric; Van Overmeere, Quentin. In-situ approaches to study hydrogen production, uptake and release on highly strained nanostructured thin films (Invited presentation). In: Proceedings of the 8th Meeting of Study of Matter at Extreme Conditions, 2015, --, p. 48. http://hdl.handle.net/2078.1/169288


Dissertations


1. Delvaux, Adeline. Electrocatalytic activity of nanostructured nickel thin film electrodes during oxygen and hydrogen evolution reactions, prom. : Proost, Joris, 20/01/2020. http://hdl.handle.net/2078.1/227673