Actualités

The cage escape yield, i.e., the separation of the geminate radical pair formed immediately after bimolecular excited-state electron transfer, was studied in 11 solvents using six Fe(III), Ru(II), and Ir(III) photosensitizers and tri-p-tolylamine as the electron donor. [Discover more...]

Excited-state quenching and reduction of [Fe(phtmeimb)2]+, where phtmeimb is phenyl[tris(3-methyl-imidazolin-2-ylidene)]borate, with iodide, bromide, and chloride were studied in dichloromethane, acetonitrile, and acetonitrile/water 1:1 mixture by means of steady-state and time-resolved spectroscopic techniques. [Discover more...]

A novel iridium(III) photosensitizer containing pyridinium-decorated terpyridines has been used for the photo-oxidation of chloride in water. Despite its abundance, the very positive one-electron reduction potential (E° Cl•/– = 2.1–2.4 V vs NHE) restricted its use in energy conversion schemes and artificial photosynthesis. [Discover more...]

The utilization of visible light to mediate chemical reactions in fluid solutions has applications that range from solar fuel production to medicine and organic synthesis. [Discover more...]

Martin GILLARD has received the 2023 IMCN Best Thesis Award on 24 May 2024. [Discover more...]