Boursier de doctorat FRIA
Timothy Steenhaut - Belgian, born in May 1994
- Dutch (native)
- French (native)
- English (fluent)
- 2012-2015 Bachelor of Applied Science, Chemistry, UCL (Belgium)
- 2015-2017 Master in Chemical science, UCL (Belgium) – Magna cum laude
- 2016-2017 Master thesis « Polyamidoamine functionalized Carbon Nanotubes » (under co-supervision of prof. Sophie Hermans and prof. Olivier Riant)
- 2016 Traineeship at KULeuven, title of research “Polyhalogenated BODIPYs” (under supervision of prof. Wim Dehaen)
- 2017-Present Ph.D. Thesis, UCL (Belgium), research on metal-organic frameworks (under supervision of prof. Sophie Hermans and prof. Yaroslav Filinchuk)
- 2017-Present Doctoral researcher at the Université catholique de Louvain (F.R.I.A. fellowship)
- 2017 Best master thesis (chemical sciences) – Université catholique de Louvain
- 2017 Solvay prize of best master thesis
- 2017 FRIA fellowship
- 2019 FRIA fellowship
- Université catholique de Louvain – LCHM1300 (“TP complémentaires”) – Supervision of the organic synthesis, mechanochemistry and powder X-ray diffraction parts of the course (2018-Present) – Elaboration of original practical work projects for bachelor students
- Supervision of traineeships, UCLouvain: 2 high school school students (2018), 3 bachelor students (1 in 2018 and 2 in 2019)
- Supervision of master theses, UCLouvain: 3 students (1 in 2018-2019 and 2 in 2019-2020)
- Student’s representative (2015-2017), UCLouvain
- Procurement manager, lab of prof. Y. Filinchuk (2017-Present), UCLouvain
- “Comité d’utilisateurs de la plateforme ASM » Representative of the labs of prof. Y. Filinchuk and S. Hermans (2019-Present), UCLouvain
- Writing and supervision of scientific projects for master theses and internships (2018-Present)
Scientific and technical skills
- Organic and inorganic syntheses and purification methods: conventional solution synthesis, development of green synthesis strategies, solventless synthesis, etc.;
- Spectroscopic techniques: NMR (liquid and solid-state), UV-vis (liquid and solid), fluorescence, Raman, IR, XPS, EDX;
- Microscopies: SEM (coupled with EDX), optical microscopies (transmission, reflection, polarization);
- Thermal analyses: TGA, DSC, TGA/DSC-MS, study of gas sorption;
- X-ray diffraction techniques: conventional powder XRD, in situ PXRD, structure resolution through PXRD, synchrotron radiation experiments;
- Textural analysis through gas sorption-desorption experiments (determination of pore size and surface area): BET and BJH methods;
- Mass spectrometry.
Year Label Educational Organization 2017 Master en sciences chimiques, à finalité approfondie Université catholique de Louvain
Syntheses and modifications of MOFs for applications in catalysis and gas storage (Doctoral thesis)
Metal-organic frameworks, commonly abbreviated as "MOF", are porous solids formed by the three-dimensional assembly of metal centers, or clusters, and bridging organic ligands. These relatively new compounds are currently of increasing interest in the scientific community. Their porosity as well as the presence of metal sites and organic ligands which can carry multiple functions make them ideal materials for a very broad scope of applications, in particular in gas storage / separation, catalysis, capture of pollutants, detection of toxic molecules, etc.
In our laboratory, we focus on the development of MOFs with a particular stability, both from a thermal point of view and with respect to solvents or to acidic and / or basic conditions. We are developing new synthetic methods to obtain these materials, in particular by respecting the principles of "Green Chemistry". The compounds thus obtained are modified in many ways, either by metal exchange and / or ligands or by functionalization of the metal sites with additional ligands. This makes it possible to obtain materials with new or improved properties compared to the starting MOF. These are mainly studied in applications in catalysis, in particular for the recovery of CO2 into molecules directly usable in industry, and in gas adsorption.
The characterization methods used for this project are very diverse and cover thermogravimetric (TGA, DSC), spectroscopic (FTIR, UV-vis, liquid and solid NMR, Raman, XPS, EXAFS, etc.), crystallographic (PXRD and single crystal diffraction, ex-situ or in-situ), chromatographic (GC, HPLC), microscopic (optical and electronic microscopy) as well as methods of study of gas adsorption at high and low pressure (BET, BJH, PCT). More specialized methods are also used for the characterization of MOFs as catalysts. The synthetic methods used bring together the conventional synthetic routes of organic and inorganic chemistry (including mechanochemistry), as well as methods requiring manipulation under controlled atmosphere and / or under pressure.
This multidisciplinary project is carried out in co-promotion with professors Sophie Hermans and Yaroslav Filinchuk (MOST, IMCN). The project is funded by two FRIA grants for a total duration of 4 years.
Steenhaut, Timothy ; Filinchuk, Yaroslav ; Hermans, Sophie. Aluminium-based MIL 100(Al) and MIL 101(Al) metal-organic frameworks, derivative materials and composites: synthesis, structure, properties and applications. In: Journal of Materials Chemistry A, (2021). doi:10.1039/d1ta04444c.
Steenhaut, Timothy ; Filinchuk, Yaroslav ; Hermans, Sophie. Aluminium-based MIL-100(Al) and MIL-101(Al) metal-organic frameworks, derivative materials and composites: synthesis, structure, properties and applications. In: J. Mater. Chem. A, Vol. none, no.none, p. none (2021) (Soumis).
Steenhaut, Timothy ; Hermans, Sophie ; Filinchuk, Yaroslav. Green synthesis of a large series of bimetallic MIL-100(Fe,M) MOFs. In: New Journal of Chemistry, no. 44, p. 3847-3855 (2020). doi:10.1039/d0nj00257g.
Steenhaut, Timothy ; Grégoire, Nicolas ; Barozzino Consiglio, Gabriella ; Filinchuk, Yaroslav ; Hermans, Sophie. Mechanochemical defect engineering of HKUST-1 and impact of the resulting defects on carbon dioxide sorption and catalytic cyclopropanation. In: RSC Advances, Vol. 10, no.34, p. 19822-19831 (2020). doi:10.1039/c9ra10412g.
Hassen, S. ; Chebbi, H. ; Arfaoui, Y. ; Robeyns, Koen ; Steenhaut, Timothy ; Hermans, Sophie ; Filinchuk, Yaroslav. Spectroscopic and structural studies, thermal characterization, optical proprieties and theoretical investigation of 2-aminobenzimidazolium tetrachlorocobaltate(II). In: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 240, p. 118612 (2020). doi:10.1016/j.saa.2020.118612.
Iakunkov, Artem ; Klechikov, Alexey ; Sun, Jinhua ; Steenhaut, Timothy ; Hermans, Sophie ; Filinchuk, Yaroslav ; Talyzin, Alexandr. Gravimetric tank method to evaluate material-enhanced hydrogen storage by physisorbing materials. In: Physical Chemistry Chemical Physics, Vol. 20, no.44, p. 27983-27991 (2018). doi:10.1039/c8cp05241g.
Desmecht, Antonin ; Steenhaut, Timothy ; Pennetreau, Florence ; Hermans, Sophie ; Riant, Olivier. Synthesis and Catalytic Applications of Multi-Walled Carbon Nanotube-Polyamidoamine Dendrimer Hybrids. In: Chemistry: A European Journal, Vol. 24, p. 12992-13001 (2018). doi:10.1002/chem.201802301.
Wang, Jian ; Steenhaut, Timothy ; Golub, Igor ; Li, Hai-Wen ; Filinchuk, Yaroslav. High yield selective synthesis of Na2B12H12 with autoclave method. Kyushu University Energy Week (Fukuoka, Japan, du 27/01/2020 au 31/01/2020).
Steenhaut, Timothy ; Filinchuk, Yaroslav ; Hermans, Sophie. Easy synthesis of complex bimetallic Metal-Organic Frameworks (Poster). IMCN Ph.D. Students' Day 2019 (Louvain-la-Neuve, Belgium, 29/05/2019).
Steenhaut, Timothy ; Hermans, Sophie ; Filinchuk, Yaroslav. How we use metal substitutions in MOFs (HKUST-1 and MIL-100). Meeting of the FNRS Contact Group for Synchrotron Radiation (Louvain-la-Neuve (Belgium), 25/04/2019).
Steenhaut, Timothy ; Louppe, Véronique ; Grégoire, Nicolas ; Hermans, Sophie ; Filinchuk, Yaroslav. Metal doping in Metal-Organic Frameworks to improve hydrogen sorption. Gordon Research Conference (GRC) on Hydrogen-Metal Systems (Castelldefels, Spain, du 30/06/2019 au 05/07/2020).