Publications
MOST
Publications
Li, Weiyang ; Liu, Cuilian ; Kfoury, Joseph ; Oláh, Julianna ; Robeyns, Koen ; Singleton, Michael L. ; Demeshko, Serhiy ; Meyer, Franc ; Garcia, Yann. A spin crossover FeII4L6 cage based on pyridyl-hydrazone sites. In: Chemical Communications, Vol. 58, no.83, p. 11653-11656 (2022). doi:10.1039/d2cc04476e.
Li, Weiyang ; Sun, Li ; Robeyns, Koen ; Rotaru, Aurelian ; Liu, Cuilian ; Singleton, Michael L. ; Garcia, Yann. Inside front cover. In: Journal of Materials Chemistry C, Vol. 10, no.24, p. 9156-9156 (2022). doi:10.1039/d2tc90125k.
Li, Weiyang ; Sun, Li ; Liu, Cuilian ; Rotaru, Aurelian ; Robeyns, Koen ; Singleton, Michael L. ; Garcia, Yann. Supramolecular FeII4L4 cage for fast ammonia sensing. In: Journal of Materials Chemistry C, Vol. 10, no.24, p. 9216-9221 (2022). doi:10.1039/d2tc01655a.
Fu, Yang ; Pichon, Benoit ; Devred, François ; Singleton, Michael L. ; Hermans, Sophie. Synthesis of spherical, rod, or chain Ni nanoparticles and their structure–activity relationship in glucose hydrogenation reaction. In: Journal of Catalysis, Vol. 415, p. 63-76 (2022). doi:10.1016/j.jcat.2022.09.028 (Accepté/Sous presse).
Fu, Yang ; Devred, François ; Eloy, Pierre ; Haynes, Tommy ; Singleton, Michael L. ; Hermans, Sophie. The effect of Ni particle size and carbon support on catalytic activity for glucose hydrogenation reaction. In: Applied Catalysis A: General, Vol. 644, p. 118833 (2022). doi:10.1016/j.apcata.2022.118833 (Accepté/Sous presse).
Aydogan, Akin ; Bangle, Rachel E. ; Cadranel, Alejandro ; Turlington, Michael D. ; Conroy, Daniel T. ; Cauët, Emilie ; Singleton, Michael L. ; Meyer, Gerald J. ; Sampaio, Renato N. ; Elias, Benjamin ; Troian-Gautier, Ludovic. Accessing Photoredox Transformations with an Iron(III) Photosensitizer and Green Light. In: Journal of the American Chemical Society, Vol. 143, no.38, p. 15661-15673 (2021). doi:10.1021/jacs.1c06081.
Liu, Ya-Zhou ; Mu, Xiao ; Chan, Chieh-Kai ; Robeyns, Koen ; Wang, Cheng-Chung ; Singleton, Michael L.. Correction: Water binding stabilizes stacked conformations of ferrocene containing sheet-like aromatic oligoamides. In: Organic & Biomolecular Chemistry, Vol. 19, no. 25, p. 5658 (2021). doi:10.1039/d1ob90079j.
Kerff, François ; Liu, Cui-Lian ; Mu, Xiao ; Gilbert, Ugo ; Smal, Louis ; Meinertzhagen, Loic ; Kauffmann, Brice ; Robeyns, Koen ; Singleton, Michael L.. Functionalized 1,8‐Diazaiptycenes as Monomers for Aromatic Oligoamide Foldamers.. In: ChemPlusChem, Vol. 86, no. 8, p. 1162-1166 (2021). doi:10.1002/cplu.202100170.
Aydogan, Akin ; Bangle, Rachel E. ; De Kreijger, Simon ; Dickenson, John C. ; Singleton, Michael L. ; Cauët, Emilie ; Cadranel, Alejandro ; Meyer, Gerald J. ; Elias, Benjamin ; Sampaio, Renato N. ; Troian-Gautier, Ludovic. Mechanistic investigation of a visible light mediated dehalogenation/cyclisation reaction using iron(iii), iridium(iii) and ruthenium(ii) photosensitizers. In: Catalysis Science & Technology, Vol. 11, no.24, p. 8037-8051 (2021). doi:10.1039/d1cy01771c.
Fu, Yang ; Ding, Lipeng ; Singleton, Michael L. ; Idrissi, Hosni ; Hermans, Sophie. Synergistic effects altering reaction pathways: The case of glucose hydrogenation over Fe-Ni catalysts. In: Applied Catalysis B: Environmental, Vol. 288, p. 119997 (2021). doi:10.1016/j.apcatb.2021.119997.
Liu, Ya-Zhou ; Mu, Xiao ; Chan, Cheih-Kai ; Robeyns, Koen ; Wang, Cheng-Chung ; Singleton, Michael L.. Water binding stabilizes stacked conformations of ferrocene containing sheet-like aromatic oligoamides. In: Organic & Biomolecular Chemistry, Vol. 19, p. 5521-5524 (2021). doi:10.1039/d1ob00580d.
Meunier, Antoine ; Singleton, Michael L. ; Kauffmann, Brice ; Granier, Thierry ; Lautrette, Guillaume ; Ferrand, Yann ; Huc, Ivan. Aromatic foldamers as scaffolds for metal second coordination sphere design. In: Chemical Science, Vol. 11, no.44, p. 12178-12186 (2020). doi:10.1039/d0sc05143h.
Liu, Cuilian ; Bobylev, Eduard O. ; Fu, Yang ; Poole, David A. ; Robeyns, Koen ; Fustin, Charles-André ; Garcia, Yann ; Reek, Joost N. H. ; Singleton, Michael L.. Balancing Ligand Flexibility Versus Rigidity for the Step‐Wise Self‐Assembly of M12L24 Via M6L12 Metal‐Organic Cages. In: Chemistry – A European Journal, Vol. 26, no. 52, p. 11960-11965 (2020). doi:10.1002/chem.202001399.
Liu, Yazhou ; Wang, Hu ; Chan, Chieh‐Kai ; Mu, Xiao ; Robeyns, Koen ; Wang, Cheng‐Chung ; Singleton, Michael L.. Structure‐Dependent Guest Recognition with Flexible Ferrocene‐Based Aromatic Oligoamide β‐Sheet Mimics. In: Chemistry – A European Journal, Vol. 26, no.1, p. 181-185 (2020). doi:10.1002/chem.201904719.
Dochain, Simon ; Nshimyumuremyi, Jean-Boris ; Dewez, Damien F. ; Body, Jean-François ; Elias, Benjamin ; Singleton, Michael L. ; Markó, István E.. Electrochemical and photochemical approaches for the synthesis of the C28–C38 fragment of okadaic acid. In: Tetrahedron, Vol. 75, no.15, p. 2280-2283 (2019). doi:10.1016/j.tet.2019.02.060.
Hammoud, A. ; Nshimyumuremyi, Jean-Boris ; Bourotte, Jérémie ; Lucaccioni, Fabio ; Robeyns, Koen ; Dirtu, Marinela ; Garcia, Yann ; Singleton, Michael L.. Cooperative Interactions in the Second Coordination Sphere of Pyridazine/Pyridine Containing Polyazaheterocyclic Iron(II) Complexes Favor Protonation. In: European Journal of Inorganic Chemistry, Vol. 2018, no. 27, p. 3253-3263 (2018). doi:10.1002/ejic.201800533.
Karier, Pol ; Catrinescu, Gheorghe C. ; Diercxsens, Nicolas ; Robeyns, Koen ; Singleton, Michael L. ; Markó, István E.. Total synthesis of (−)-cleistenolide and formal synthesis of herbarumin I via a diastereoselective modulable allylation. In: Tetrahedron, Vol. 74, no.51, p. 7242-7251 (2018). doi:10.1016/j.tet.2018.10.063.
Singleton, Michael L. ; Aydogan, Akin ; Bourotte, Jérémie ; Hammoud, Ahmad ; Hoteite, Larry ; Kopf, Kenji ; Mu, Xiao. Taking inspiration from biology to explore new chemical reactivity. In: Chimie Nouvelle, Vol. 123, p. 1.
Singleton, Michael L. ; Pirotte, Geert ; Kauffmann, Brice ; Huc, Ivan. Increasing the size of an aromatic helical foldamer cavoty by strand intercalation. In: Angewandte Chemie (International Edition), Vol. 53, p. 13140-13144 (2014). doi:10.1002/anie.201407752.
Singleton, Michael L. ; Castellucci, Nicola ; Massip , Stéphane ; Kauffmann, Brice ; Ferrand, Yann ; Huc, Ivan. Synthesis of 1,8-diazaanthracenes as building blocks for internally functionalized aromatic oligoamide foldamers. In: The Journal of Organic Chemistry, Vol. 79, p. 2115-2122 (2014). doi:10.1021/jo402852m | J.
Stoian, Sébastien A. ; Hsieh, Chung-Hung ; Singleton, Michael L. ; Casuras, Andrea F. ; Darensbourg, Marcetta Y. ; McNeely, Kelsey ; Sweely, Kurt ; Popescu, Codrina V.. Hyperfine interactions and electron distribution in FeIIFeI and FeIFeI models for the active site on the [FeFe]-hydrogenases : Mössbauer spectroscopy studies of low-spin FeI. In: Journal of Biological Inorganic Chemistry, Vol. 18, p. 609-622 (2013). doi:10.1007/s00775-013-1005-5.
Hsieh, C.-H. ; Erdem, O.F. ; Harman, S.D. ; Singleton, Michael L. ; Reijerse, E. ; Lubitz, W. ; Popescu, C.V. ; Reibenspies, J. H. ; Brothers, S.M. ; Hall, M.B. ; Darensbourg, M.Y.. Structural and Spectroscopic Features of Mixed Valent FeIIFeI Complexes and Factors Related to the Rotated Configuration of Diiron Hydrogenase. In: Journal of the American chemical society, Vol. 134, p. 13089-13102 (2012). doi:10.1021/ja304866r.
Singleton, Michael L. ; Crouthers, D.J. ; Duttweiler, R.P. ; Reibenspies, J.H. ; Darensbourg, M.Y.. Sulfonated Diiron Complexes as Water-Soluble Models of the [FeFe]-Hydrogenase Enzyme Active Site. In: Inorganic Chemistry, Vol. 50, p. 5015-5026 (2011). doi:10.1021/ic200272x.
Singleton, Michael L. ; Reibenspies, J.H. ; Darensbourg, M.Y.. A Cyclodextrin Host/Guest Approach to a Hydrogenase Active Site Biomimetic Cavity. In: Journal of the American chemical society, Vol. 132, p. 8870-8871 (2010). doi:10.1021/ja103774j.
Jenkins, R.M. ; Singleton, Michael L. ; Leamer, L.A. ; Reibenspies, J.H. ; Darensbourg, M.Y.. Orientation and Stereodynamic Paths of Planar Monodentate Ligands in Square Planar Nickel N2S Complexes. In: Inorganic Chemistry, Vol. 49, p. 5503-5514 (2010). doi:10.1021/ic1002012.
Bethel, R.D. ; Singleton, Michael L. ; Darensbourg, M.Y.. The Modular Assembly of Clusters Is the Natural Synthetic Strategy for the Active Site of [FeFe] Hydrogenase. In: Angewandte Chemie (International Edition), Vol. 49, p. 8567-8569 (2010). doi:10.1002/anie.201003747.
Smal, Louis ; Singleton, Michael L.. A Diels-Alder strategy for controlling self-assembly of aromatic oligoamide multi-stranded helices. BOSS 2022 (Namur, du 04/07/2022 au 08/07/2022).
Smal, Louis ; Singleton, Michael L.. A Diels-Alder/retro-Diels-Alder strategy for controlling self-assembly of aromatic oligoamide multi-stranded helices. ICAMANA 2022 (UCL + Online, du 22/11/2022 au 24/11/2022).
Gilbert, Ugo ; Singleton, Michael L. ; Robiette, Raphaël. Experimental and theoretical studies into the structural importance of the imine versus the amine function of the histidine brace motif of LPMO’s. BOSS 2022 (UNamur, du 04/07/2022 au 08/07/2022).
Singleton, Michael L.. Reversible Conformational Changes and Metal Coordination Allow the Controlled Self-assembly of Aromatic Amides. Workshop on aromatic foldamers - 2022 (Leeds, United Kingdom, du 21/04/2022 au 22/04/2022).
Smal, Louis ; Singleton, Michael L.. Social self-sorting control in the self-assembly of aromatic oligoamide multiple helices. MOCS 2022 (Blankenberg, du 01/12/2022 au 02/12/2022).
Li, Weiyang ; Liu, Cuilian ; Singleton, Michael L. ; Garcia, Yann. Spin crossover FeII4L4 supramolecular cage for fast ammonia sensing . GFSM 2022 (Nancy, du 17/05/2022 au 19/05/2022).
Pochet, Corentin ; Singleton, Michael L.. Towards the synthesis of ligand scaffold for bimetallic systems. Merck Oorganic Chenistry Symposium 2022 (Blankenberge, du 01/12/2022 au 02/12/2022).
Pochet, Corentin ; Singleton, Michael L.. Towards the synthesis of ligands scaffold for cooperative bimetallic systems. Belgian Organic Synthesis Symposium 2022 (Namur, du 03/07/2022 au 08/07/2022).
Smal, Louis ; Singleton, Michael L.. A Diels-Alder / retro-Diels-Alder strategy for controlling self-assembly of aromatic oligoamide double helices. MOCS 2021 (Online, 23/12/2021).
Kerff, François ; Singleton, Michael L.. A Diels-Alder/Retro Diels-Alder approach for controlling hybridization of aromatic oligoamide foldamers into multiple helices. Bordeaux Foldamer Symposium 2021 (Bordeaux, France, du 13/09/2021 au 15/09/2021).
Gilbert, Ugo ; Singleton, Michael L. ; Robiette, Raphaël. Experimental and theoretical studies into the structural importance of the histidine brace motif of LPMO's. MOCS 2021 (UClouvain, 03/12/2021).
Li, Weiyang ; Liu, Cuilian ; Singleton, Michael L. ; Garcia, Yann. Supramolecular FeII4L6 Cages Based on Pyridyl-Imine Sites: Subcomponent Self-Assembly and Spin Crossover Property. EDT CHIM 2021 (Brussels (online)).
Aydogan, Akin ; Singleton, Michael L. ; Elias, Benjamin. Toward Hydrogen Photo-evolution from Iron-based Photosensitizer . One-day meeting of Young Chemists 2020 (Namur, Belgium, 06/03/2020).
Singleton, Michael L.. Controlling Structure and Self-Assembly Pathways in Bioinspired Self-Organized Molecules. International conference on advanced materials, nanosciences, and applications (ICAMANA 2019) (Oujda, Morocco, du 10/12/2019 au 13/12/2019).
Aydogan, Akin ; Singleton, Michael L. ; Elias, Benjamin. Covalent and Non-covalent Interactions for Iron-based Photocatalysis . Merck Organic Chemistry Symposium 2019 (Blankenberge, du 05/12/2019 au 06/12/2019).
Aydogan, Akin ; Elias, Benjamin ; Singleton, Michael L.. Iron-based Photocatalysis and Combined reactivity with Organocatalyst and Guanidinium». PhD Students'Day 2019 (Louvain-la-Neuve (Belgium), 29/05/2019).
Liu, Cuilian ; Garcia, Yann ; Singleton, Michael L.. Non-Covalent Interactions direct self-assembly of Supramolecular Metal-Organic Cages. IMCN PhD student’s day (Louvain-la-Neuve (Belgium), 29/05/2019).
Xiao Mu ; Singleton, Michael L.. Assembly of Discrete Aromatic Stacks through Complimentary Hydrogen Bonding with DNA/RNA Oligomers. Supr@lyon (Lyon, France, du 12/12/2018 au 14/12/2018).
Singleton, Michael L.. Cooperativity and recognition in bioinspired self-organized molecules. Merck Organic Chemistry Symposium (Blankenberge, Belgium, du 06/12/2018 au 07/12/2018).
Liu, Cuilian ; Garcia, Yann ; Singleton, Michael L.. Coordination Driven Self-assembly towards Directional Construction of Functional Supramolecular Architectures. SRC 2018 – Chemistry of bio-sourced molecules and materials (Mons (Belgium), 11/10/2018).
Aydogan, Akin ; Schott, Olivier ; Hanan, Garry S. ; Singleton, Michael L. ; Elias, Benjamin. Design and Studies of Novel Iron-based Complexes for Hydrogen Photo-evolution. SupraLyon (Lyon (France), du 12/12/2018 au 14/12/2018).
Aydogan, Akin ; Schott, Olivier ; Hanan, Garry S. ; Singleton, Michael L. ; Elias, Benjamin. Design and Studies of Novel Iron-based Complexes for Hydrogen Photo-evolution . Merck Organic Chemistry Symposium 2018 (Blankenberge, du 06/12/2018 au 07/12/2018).
yazhou liu ; Singleton, Michael L.. Design and Synthesis of Biomimetic β-sheets Ferrocene Derivatives. Bordeaux Foldamer Symposium 2018 (Bordeaux, France, du 24/09/2018 au 26/09/2018).
Liu, Cuilian ; Garcia, Yann ; Singleton, Michael L.. Incorporating Flexible Supermolecules and Endohedral Binding Sties in Self-assembled Nanocontainers. Symposium Supr@Lyon (Lyon (France), du 12/12/2018 au 14/12/2018).
Liu, Cuilian ; Garcia, Yann ; Singleton, Michael L.. Self-assembly of Flexible Supermolecules with Endohedral Binding Sties towards Nanocontainers and Sensors. BCS-10 (Brussels (Belgium), 17/10/2018).
Liu, Cuilian ; Garcia, Yann ; Singleton, Michael L.. Self-assembly of flexible supermolecules with endohedral binding sties towards nanocontainers and sensors (poster). 6th Bordeaux Symposium on Foldamers 2018 (Bordeaux (France), du 24/09/2018 au 26/09/2018).
Liu, Cuilian ; Garcia, Yann ; Singleton, Michael L.. Self-assembly of flexible supermolecules with endohedral binding sties towards nanocontainers and sensors (poster). BOSS XVI (Bruxelles (Belgium), du 08/07/2018 au 13/07/2018).
Liu, Cuilian ; Garcia, Yann ; Singleton, Michael L.. Self-assembly of functional porous networks driven by formation of double and higher order helical foldamers (poster). ACIN 2018 (Namur (Belgium), du 16/07/2018 au 20/07/2018).
Mu, Xiao ; Bourotte, Jérémie ; Riant, Olivier ; Singleton, Michael L.. Biomimetics and biohybrid structures as tools for controlling molecular structure (poster). Merck Organic Symposium - MOCS 2017 (Blankenberge (Belgium), du 07/12/2017 au 08/12/2017).
Aydogan, Akin ; Elias, Benjamin ; Singleton, Michael L.. Iron and cobalt based heterotrimetallic complexes designed for hydrogen photoproduction (poster). Merck Organic Symposium - MOCS 2017 (Blankenberge (Belgium), du 07/12/2017 au 08/12/2017).
Aydogan, Akin ; Elias, Benjamin ; Singleton, Michael L.. Iron based photoredox catalysis (poster). Journée Scientifique SRC 2017 - Chimie et molécules du vivant (Louvain-la-Neuve (Belgium), 12/10/2017).
Aydogan, Akin ; Elias, Benjamin ; Singleton, Michael L.. Iron based photoredox catalysis (poster). Journée Rencontre des Jeunes Chimistes de la SRC (10e édition) (Louvain-la-Neuve (Belgium), 31/03/2017).
Liu, Cuilian ; Garcia, Yann ; Singleton, Michael L.. Self-assembly of Polygons Driven by Formation of Double Helical Foldmers (poster). 21st Merck Organic Chemistry Symposium (Blankenberge (Belgium), du 07/12/2017 au 08/12/2017).
Aydogan, Akin ; Elias, Benjamin ; Singleton, Michael L.. Iron based photoredox catalysis (poster). 20th Sigma-Aldrich Symposium (Blankenberge (Belgium), du 08/12/2016 au 09/12/2016).
Aydogan, Akin ; Hammoud, Ahmad ; Lentz, Cédric ; Elias, Benjamin ; Singleton, Michael L.. Cooperative metal redox photoreactivity based on ditopic scaffolds (poster). 19th SIGMA-ALDRICH Symposium (Blankenberghe (Belgum), du 10/12/2015 au 11/12/2015).
Singleton, Michael L. ; Lautrette, G. ; Ferrand, Y. ; Kauffmann, B. ; Huc, I.. Aromatic oligoamides as second coordination sphere mimics for biologically inspired catalysts (poster) . Metals in Biology Gordon Research Conference (Ventura (USA), du 26/01/2013 au 31/01/2013).
Singleton, Michael L. ; Lautrette, G. ; Ferrand, Y. ; Kauffmann, B. ; Huc, I.. Catalytic foldamers developing artificial metalloenzymes for hydrogen productions (poster - Awarded first place). 6th IECB Young Scientist Symposium (Bordeaux (France), du 27/05/2013 au 28/05/2013).
Singleton, Michael L. ; Lautrette, G. ; Ferrand, Y. ; Kauffmann, B. ; Huc, I.. Catamers: Developing artificial metalloenzymes for hydrogen production (poster). 16th International Conference on Biological Inorganic Chemistry (Grenoble (France), du 22/07/2013 au 26/07/2013).
Singleton, Michael L. ; Lautrette, G. ; Ferrand, Y. ; Kauffmann, B. ; Huc, I.. Helical aromatic oligoamide foldamers as synthetic second coordination spheres for biologically inspired hydrogen production catalysts (poster). Paris Symposium on Foldamers (Paris (France), du 10/04/013 au 12/04/2013).
Singleton, Michael L. ; Ferrand, Y. ; Huc, I.. Structural (and spectroscopic) insights on the effects of non-covalent interactions on biomimetics of [FeFe]-hydrogenase. JABC6 - 6° Journées de l'Association Bordelaise de Cristallographie (Bordeaux (France), du 21/06/2012 au 22/06/2012).
Singleton, Michael L. ; Ferrand, Y. ; Huc, I.. Aromatic oligoamides for application in artificial second coordination sphere design. ArtZymes 2011 (Marseille (France), du 25/09/2011 au 28/09/2011).
Singleton, Michael L. ; Darensbourg, M.Y.. Effect of inclusion in cyclodextrins on small molecule models of [FeFe]-hydrogenase. 239th ACS National Meeting (San Francisco (USA), du 21/03/2010 au 25/03/2010).
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